1.4 研究目的及大綱

本章的研究綜述已經(jīng)說(shuō)明壓力在熱力學(xué)中是一個(gè)重要的變量，可導(dǎo)致材料發(fā)生各種相變。同時(shí)受壓力和溫度作用時(shí)相變行為會(huì)更活躍。壓力或溫度引發(fā)的相變可極大程度地影響含能材料的特性。因此，表征極端條件下的含能材料所有晶型結(jié)構(gòu)都十分重要。本研究的目的在于：

（1）研究壓力、壓力和溫度對(duì)含能材料的多種晶型的影響。

（2）在實(shí)驗(yàn)過(guò)程中鑒定和表征新晶型。

（3）探究高壓相變材料是否能在常壓回收，進(jìn)一步設(shè)想在室溫常壓下是否能獲取高性能含能材料。

第3章將描述結(jié)合振動(dòng)光譜和粉末X射線衍射表征高溫/高壓RDX多晶型，還將描述室壓下高度亞穩(wěn)定晶型的結(jié)構(gòu)。第4章探究不同傳壓介質(zhì)下的CL-20的高壓相變行為。第5章和第6章描述了在一系列壓力和溫度條件影響下無(wú)機(jī)疊氮化物的結(jié)構(gòu)表征。每一部分都含有對(duì)相關(guān)研究的展望。第7章為全書(shū)總結(jié)以及對(duì)極端條件下含能材料研究的展望。

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